ZnAlF5·[TAZ]: An Al fluorinated MOF of MIL-53(Al) topology with cationic {Zn(1,2,4 triazole)}2+ linkers

Amandine Cadiau, Charlotte Martineau, Marc Leblanc, Vincent Maisonneuve, Annie Hémon-Ribaud, Francis Taulelle, Karim Adil*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

ZnAlF5·[TAZ], the first aluminium fluorinated metal-organic framework with cationic {Zn(1,2,4 triazole)}2+ linkers has been synthesized. The structure is accurately determined by coupling direct space methods on laboratory powder X-ray diffraction data with solid-state nuclear magnetic resonance experiments and ab initio calculations, and is found to be analogous to that of MIL-53(Al).

Original languageEnglish (US)
Pages (from-to)3949-3951
Number of pages3
JournalJournal of Materials Chemistry
Volume21
Issue number11
DOIs
StatePublished - Jan 1 2011

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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