Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane

Bilel Hamzaoui, Mohamad El Eter, Edy Abou-Hamad, Yin Chen, Jeremie Pelletier, Jean-Marie Basset

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
Original languageEnglish (US)
Pages (from-to)4294-4299
Number of pages6
JournalChemistry - A European Journal
Volume21
Issue number11
DOIs
StatePublished - Jan 13 2015

ASJC Scopus subject areas

  • Chemistry(all)

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