Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Mohamad El Eter, Bilel Hamzaoui, Edy Abou-Hamad, Jeremie Pelletier, Jean-Marie Basset

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.
Original languageEnglish (US)
Pages (from-to)4616
JournalChemical Communications
Volume49
Issue number41
DOIs
StatePublished - 2013

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Ceramics and Composites
  • Chemistry(all)
  • Catalysis
  • Electronic, Optical and Magnetic Materials

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