Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

Jérôme Boulanger, Hervé Bricout, Sébastien Tilloy, Aziz Fihri, Christophe Len, Frédéric Hapiot, Éric Monflier

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.
Original languageEnglish (US)
Pages (from-to)77-81
Number of pages5
JournalCatalysis Communications
Volume29
DOIs
StatePublished - Dec 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Process Chemistry and Technology

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