Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

Seema Arun Ghorpade, Dinesh Sawant, Arwa Makki, N Sekar, Jörg Eppinger

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Transition metal free, water based, greener protocol for allylic alkylation, allylic amination, O-allylation of (E)-1,3-diphenylallyl acetate is described. The developed methodology is applicable for a wide range of nucleophiles furnishing excellent yields of corresponding products up to 87% under mild reaction conditions. A Distinct effect of water and base is explored for allylic nucleophilic substitution reactions of (E)-1,3-diphenylallyl acetate.
Original languageEnglish (US)
Pages (from-to)425-430
Number of pages6
JournalGreen Chemistry
Volume20
Issue number2
DOIs
StatePublished - 2018

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