Use of branched aliphatic linkers for the preparation of selective chiral media for the HPLC separation of enantiomers

Yuelong Liu, Kathleen N. Juneau, Frantisek Svec, Jean Frechet*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Highly branched aliphatic molecules have been used for the first time as tethers in the preparation of polymeric chiral stationary phases. Attachment of a specifically designed chiral selector to organic porous polymer beads through a branched linker substantially increases the enantioselectivity compared to that of the equivalent separation medium with a traditional linear tether.

Original languageEnglish (US)
Pages (from-to)183-189
Number of pages7
JournalPolymer Bulletin
Volume41
Issue number2
DOIs
StatePublished - Jan 1 1998

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Polymers and Plastics
  • Materials Chemistry

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