Trialkyl tin salts of polyoxometalates: Synthesis and characterization of [α-SiW12O40][(CH3)3Sn(DMSO)2]4·2DMSO

Nicolas Legagneux, Erwann Jeanneau, Jean-Marie Maurice Basset, Frédéric Lefebvre*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Tetramethyl tin reacts with dodecatungstosilicic acid H4SiW12O40 in anhydrous DMSO with evolution of methane to yield the trimethyl tin salt of the heteropolyoxometalate [α-SiW12O40][(CH3)3Sn(DMSO)2]4·2DMSO. The structure has been determined by X-ray diffraction and shows that there is no direct bond between the polyoxometalate and the tin complex. 119Sn NMR indicates that tin has quite the same coordination in the solid state and in DMSO solution.

Original languageEnglish (US)
Pages (from-to)300-306
Number of pages7
JournalJournal of Molecular Structure
Volume921
Issue number1-3
DOIs
StatePublished - Mar 17 2009

Keywords

  • Alkyltin
  • Heteropolyoxometalates
  • Sn NMR
  • X-ray diffraction

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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