Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

Mirza Cokoja, Christian Bruckmeier, Bernhard Rieger, Wolfgang A. Herrmann, Fritz E. Kühn

Research output: Contribution to journalArticlepeer-review

1195 Scopus citations

Abstract

A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, considerable research has been performed to find catalytic routes to transform CO 2 into carboxylic acids, esters, lactones, and polymers in an economic way. This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C 1 carbon source for the synthesis of industrial products as well as fine chemicals. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish (US)
Pages (from-to)8510-8537
Number of pages28
JournalAngewandte Chemie International Edition
Volume50
Issue number37
DOIs
StatePublished - Aug 29 2011
Externally publishedYes

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