Towards syntheses and structures of heterometallic clusters containing tantalum-tetrachalcogenato building blocks

Dieter Fenske*, Ibrahim Issac, Alexander Rothenberger

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

An approach to tackle the synthesis of mixed-transition metal tantalum chalcogenide clusters is described. The synthesis of 1/ [Li3(TaSe4)(MeCN)4] (1) will in future allow the construction of Ta-Se-transition metal clusters. The potential of this route was demonstrated by the synthesis of the mixed-metal Ta-S-Fe and Ta-S-Cu complexes (Et4N) 3[Fe2(SPh)4(TaS4)] (2) and [Cu 3(TaS4)(PPh3)4] (3).

Original languageEnglish (US)
Pages (from-to)19-26
Number of pages8
JournalJournal of Cluster Science
Volume18
Issue number1
DOIs
StatePublished - Mar 1 2007

Keywords

  • Crystal structure
  • Heterometallic chalcogenides
  • Iron
  • Tantalum

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry
  • Materials Science(all)
  • Condensed Matter Physics

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