Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

Hala Assi, Georges Mouchaham, Nathalie Steunou, Thomas Devic, Christian Serre

Research output: Contribution to journalArticlepeer-review

153 Scopus citations

Abstract

Owing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.
Original languageEnglish (US)
Pages (from-to)3431-3431
Number of pages1
JournalChem. Soc. Rev.
Volume46
Issue number11
DOIs
StatePublished - May 24 2017

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