Thermodynamics of TMPC/PSd/Fullerene Nanocomposites: SANS Study

Yang-Choo Chua, Alice Chan, Him-Cheng Wong, Julia S. Higgins, João T. Cabral

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Wereport a small angle neutron scattering study of the thermodynamics of a polymer mixture in the presence of nanoparticles, both in equilibrium and during phase separation. Neutron cloud point measurements and random phase approximation (RPA) analysis demonstrate that 1-2 mass % of C60 fullerenes destabilizes a highly interacting mixture of poly(tetramethyl bisphenol A polycarbonate) and deuterated polystyrene (TMPC/PSd). We unequivocally corroborate these findings with time-resolved temperature jump experiments that, in identical conditions, result in phase separation for the nanocomposite and stability for the neat polymer mixture. At lower C 60 loadings (viz. 0.2-0.5 mass %), stabilization of the mixture is observed. The nonmonotonic variation of the spinodal temperature with fullerene addition suggests a competitive interplay of asymmetric component interactions and nanoparticle dispersion. The stability line shift depends critically on particle dispersion and vanishes upon nanoparticle agglomeration. © 2010 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)9578-9582
Number of pages5
JournalMacromolecules
Volume43
Issue number22
DOIs
StatePublished - Nov 23 2010
Externally publishedYes

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