Theoretical study of energy transfer in Rb(7S) + Rb(5S) and Rb(5D) + Rb(5S) collisions

K. Orlovsky*, V. Grushevsky, Aigars Ekers

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

We present results of theoretical studies of the non-resonant excitation transfer in Rb(7S) + Rb(5S) and Rb(5D) + Rb(5S) collisions at thermal collision energies. Rb2 adiabatic molecular terms correlating with the 5S+7S, 5S+5D and 5P+5P states of separated atoms were calculated for internuclear distances R > 20 a.u. using asymptotic approximation. Mechanisms of collisional population and quenching of the 5D state were treated on the basis of the computed molecular terms, and the respective cross-sections were calculated. Theoretical cross-sections are in good agreement with the experimental values at thermal collision energies (T ∼ 500 K).

Original languageEnglish (US)
Pages (from-to)133-146
Number of pages14
JournalEuropean Physical Journal D
Volume12
Issue number1
DOIs
StatePublished - Jan 1 2000

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

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