TY - JOUR
T1 - Tetraphenylethene-Functionalized Polyethylene-Based Polymers with Aggregation-Induced Emission
AU - Jiang, Yu
AU - Hadjichristidis, Nikos
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors thank Dr. Panagiotis Bilalis for his help with the investigation of self-assembly. The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
PY - 2019/2/25
Y1 - 2019/2/25
N2 - A novel synthetic strategy toward a series of tetraphenylethene (TPE)-functionalized polyethylene-based homo/copolymers is presented. Tris(3-(4-(1,2,2-triphenylvinyl)phenoxy)propyl)borane, synthesized by hydroboration of (2-(4-(allyloxy)phenyl)ethene-1,1,2-triyl)tribenzene with BH3, was used to initiate the polyhomologation of dimethylsulfoxonium methylide to afford well-defined TPE-terminated linear polyethylene (PE). Combining this efficient strategy with ring-opening polymerization (ROP) or atom transfer radical polymerization (ATRP), TPE-functionalized PE-based block copolymers have been synthesized. All synthesized polymers showed aggregation-induced emission (AIE) behavior either in solution or in bulk. Self-assembly of the PE-based block copolymer in DMF resulted in strong emission due to the AIE effect of the aggregated TPE-PM core; the fluorescence intensity of the solution is directly related to the composition of block copolymers and the size of the micelle. The response of the AIE-operative fluorescence behavior in terms of concentration of the block copolymer solutions has also been used to locate the critical micelle concentration (CMC) value of the block copolymers. The nonemissive dilute solutions of block copolymers became fluorescent when increasing concentrations above the CMC.
AB - A novel synthetic strategy toward a series of tetraphenylethene (TPE)-functionalized polyethylene-based homo/copolymers is presented. Tris(3-(4-(1,2,2-triphenylvinyl)phenoxy)propyl)borane, synthesized by hydroboration of (2-(4-(allyloxy)phenyl)ethene-1,1,2-triyl)tribenzene with BH3, was used to initiate the polyhomologation of dimethylsulfoxonium methylide to afford well-defined TPE-terminated linear polyethylene (PE). Combining this efficient strategy with ring-opening polymerization (ROP) or atom transfer radical polymerization (ATRP), TPE-functionalized PE-based block copolymers have been synthesized. All synthesized polymers showed aggregation-induced emission (AIE) behavior either in solution or in bulk. Self-assembly of the PE-based block copolymer in DMF resulted in strong emission due to the AIE effect of the aggregated TPE-PM core; the fluorescence intensity of the solution is directly related to the composition of block copolymers and the size of the micelle. The response of the AIE-operative fluorescence behavior in terms of concentration of the block copolymer solutions has also been used to locate the critical micelle concentration (CMC) value of the block copolymers. The nonemissive dilute solutions of block copolymers became fluorescent when increasing concentrations above the CMC.
UR - http://hdl.handle.net/10754/652999
UR - https://pubs.acs.org/doi/10.1021/acs.macromol.9b00121
UR - http://www.scopus.com/inward/record.url?scp=85062843128&partnerID=8YFLogxK
U2 - 10.1021/acs.macromol.9b00121
DO - 10.1021/acs.macromol.9b00121
M3 - Article
AN - SCOPUS:85062843128
VL - 52
SP - 1955
EP - 1964
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 5
ER -