Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Wangdong Zeng, Byungsun Lee, Youngmo Sung, Kuo-Wei Huang, Yuan Li, Dongho Kim, Jishan Wu

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.
Original languageEnglish (US)
Pages (from-to)7684
JournalChemical Communications
Volume48
Issue number62
DOIs
StatePublished - 2012

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Ceramics and Composites
  • Chemistry(all)
  • Catalysis
  • Electronic, Optical and Magnetic Materials

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