Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material

Zhenjie Zhang, Linping Zhang, Łukasz Wojtas, Patrick S. Nugent, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journalArticlepeer-review

198 Scopus citations

Abstract

Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)924-927
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number2
DOIs
StatePublished - Dec 28 2011

ASJC Scopus subject areas

  • Biochemistry
  • Colloid and Surface Chemistry
  • Chemistry(all)
  • Catalysis

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