Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

Christopher E. Anson, Lukasz Ponikiewski, Alexander Rothenberger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The preparation and characterisation of the Cu(I) aryloxides [Cu16(3-pyO)16(dppm)8] (1), [{Cu2(2-pyO)2(dppm)}2] (2) and [{Cu33-6-OQ)2(dppm)3}{(6-HOQ)2(μ-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/[Cu3(3-pyO)(CO2C2H4Boc)(dppm-)(dppm)] (4) (Boc = tert-butoxycarbonyl).

Original languageEnglish (US)
Pages (from-to)2263-2267
Number of pages5
JournalInorganica Chimica Acta
Volume359
Issue number7
DOIs
StatePublished - Apr 25 2006

Keywords

  • Insertion reaction
  • Metal alkoxide
  • Organic anhydride

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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