Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand

Bradley M. Kraft, Kuo-Wei Huang, Adam P. Cole, Robert M. Waymouth*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl]phenolato(2-) -2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.

Original languageEnglish (US)
Pages (from-to)1589-1595
Number of pages7
JournalHelvetica Chimica Acta
Volume89
Issue number8
DOIs
StatePublished - Sep 14 2006

ASJC Scopus subject areas

  • Catalysis
  • Biochemistry
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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