Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

Maxim Yutkin, Marina S. Zavakhina, Alexander V. Virovets, Danil N. Dybtsev, Vladimir P. Fedin, Tetsuro Kusamoto, Hiroshi Nishihara

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

New metal-organic coordination polymer, (Me3NH)[Fe 33-O)(μ-HCOO)8]·DMF (1), was synthesized by heating of Fe(NO3)3·9H2O and [NH(CH3)3]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(μ-HCOO)6 cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between FeIII ions in the cluster and intercluster magnetic interaction.

Original languageEnglish (US)
Pages (from-to)513-516
Number of pages4
JournalInorganica Chimica Acta
Volume365
Issue number1
DOIs
StatePublished - Jan 15 2011

Keywords

  • Coordination polymers
  • Iron(III) complexes
  • Magnetic properties
  • Metal-organic formates
  • X-ray single-crystal analysis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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