Synthesis, Structural Characterization and Thermal Behavior of New Organic–Inorganic Sulfate

Sami Soukrata*, Mohamed Belhouchet, Karim Adil, Tahar Mhiri

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The new organic–inorganic compound has been synthesized and characterized by X-ray single crystal, infra-red, Raman spectroscopy and thermal investigations. It crystallizes in the monoclinic space group P21 with following unit cell dimensions: a = 4.5542(2) Å, b = 10.5171(5) Å, c = 13.7373(6) Å, β = 93.936(2)°, Z = 2 and V = 656.42(5) Å3. The crystal structure has been determined and refined to R1 = 0.0395 and wR2 = 0.1143 using 3950 independent reflections. The atomic arrangement is defined by infinite anionic chains running parallel to the [100] direction. These last are interconnected to the organic cation by hydrogen bonds N–H…O to form a one dimensional network.

Original languageEnglish (US)
Pages (from-to)1413-1424
Number of pages12
JournalJournal of Cluster Science
Volume26
Issue number4
DOIs
StatePublished - Dec 13 2015
Externally publishedYes

Keywords

  • Chemical synthesis
  • Crystal structure
  • Inorganic compounds
  • NMR spectroscopy
  • Thermal analysis

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry
  • Materials Science(all)
  • Condensed Matter Physics

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