Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Xiufang Wang; Liangfeng Yao; Yupeng Pan; Kuo-Wei Huang

doi:10.1016/j.jorganchem.2016.12.032

Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Xiufang Wang, Liangfeng Yao, Yupeng Pan, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

Original language	English (US)
Pages (from-to)	25-29
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	845
DOIs	https://doi.org/10.1016/j.jorganchem.2016.12.032
State	Published - Jan 1 2017

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10.1016/j.jorganchem.2016.12.032

https://repository.kaust.edu.sa/bitstream/10754/622628/1/1-s2.0-S0022328X16305939-main.pdf

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CCDC 1563148: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)
Wang, X. (Creator), Yao, L. (Creator), Pan, Y. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Jul 31 2017
DOI: 10.5517/ccdc.csd.cc1pgl4w, http://hdl.handle.net/10754/663700
Dataset
CCDC 1563147: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-palladium(ii)
Wang, X. (Creator), Yao, L. (Creator), Pan, Y. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Jul 31 2017
DOI: 10.5517/ccdc.csd.cc1pgl3v, http://hdl.handle.net/10754/663699
Dataset
CCDC 1563151: Experimental Crystal Structure Determination : chloro-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-palladium(ii)
Wang, X. (Creator), Yao, L. (Creator), Pan, Y. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Jul 31 2017
DOI: 10.5517/ccdc.csd.cc1pgl7z, http://hdl.handle.net/10754/663694
Dataset

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@article{113f6af5975040e9adcc747811b9be6d,

title = "Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity",

abstract = "A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.",

author = "Xiufang Wang and Liangfeng Yao and Yupeng Pan and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by King Abdullah University of Science and Technology (KAUST). We thank Dr. Jinsong Hu and Carolyn E. Unck for assistance with the manuscript preparation.",

year = "2017",

month = jan,

day = "1",

doi = "10.1016/j.jorganchem.2016.12.032",

language = "English (US)",

volume = "845",

pages = "25--29",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

AU - Wang, Xiufang

AU - Yao, Liangfeng

AU - Pan, Yupeng

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by King Abdullah University of Science and Technology (KAUST). We thank Dr. Jinsong Hu and Carolyn E. Unck for assistance with the manuscript preparation.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

AB - A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

UR - http://hdl.handle.net/10754/622628

UR - http://www.sciencedirect.com/science/article/pii/S0022328X16305939

UR - http://www.scopus.com/inward/record.url?scp=85008514531&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2016.12.032

DO - 10.1016/j.jorganchem.2016.12.032

M3 - Article

VL - 845

SP - 25

EP - 29

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Abstract

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CCDC 1563148: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)

CCDC 1563147: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-palladium(ii)

CCDC 1563151: Experimental Crystal Structure Determination : chloro-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-palladium(ii)

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