Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Alexander L. Kanibolotsky, Lyudmila Kanibolotskaya, Sergey Gordeyev, Peter J. Skabara*, Iain Mcculloch, Rory Berridge, Jan E. Lohr, Filippo Marchioni, Fred Wudl

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

Original languageEnglish (US)
Pages (from-to)1601-1604
Number of pages4
JournalOrganic Letters
Volume9
Issue number8
DOIs
StatePublished - Apr 12 2007

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Fingerprint

Dive into the research topics of 'Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units'. Together they form a unique fingerprint.

Cite this