Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

Bin Gu, Chenglin Sun, James C. Fettinger, William H. Casey, Alla Dikhtiarenko, Jorge Gascon, Kamila Koichumanova, Karthick Babu Sai Sankar Gupta, Hero Jan Heeres, Songbo He

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.
Original languageEnglish (US)
Pages (from-to)4148-4151
Number of pages4
JournalChemical Communications
Volume54
Issue number33
DOIs
StatePublished - 2018

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