Synthesis, characterization and propane metathesis activity of a tantalum-hydride prepared on high surface area "silica supported zirconium hydroxide"

Franck Rataboul*, Christophe Copéret, Laurent Lefort, Aimery De Mallmann, Jean Thivolle-Cazat, Jean-Marie Maurice Basset

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

A new tantalum-hydride supported on zirconium hydroxide [(SiO) 2Zr(H)-O-Ta(H)x-(OSi)] (x = 1 or 3) was prepared using surface organometallic chemistry and its catalytic properties in the propane metathesis reaction were assessed showing improved activity and selectivities in comparison to the tantalum-hydride supported on silica.

Original languageEnglish (US)
Pages (from-to)923-927
Number of pages5
JournalDalton Transactions
Issue number9
DOIs
StatePublished - Jan 1 2007

ASJC Scopus subject areas

  • Inorganic Chemistry

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