Synthesis and structures of two new coordination polymers formed by large polyoxometalate fragments and lanthanide cations

N. V. Izarova, M. N. Sokolov, D. G. Samsonenko, Alexander Rothenberger, D. Fenske, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The reactions of the polyoxometalate [Mo36O108(NO) 4(H2O)16]12- with EuCl 3• 6H2O and Tm2(SO4) 3 • 8H2O afford the coordination polymers with the following composition: (H3O)3.67{Eu(H2O) 4}{Eu(H2O)6}2 {Mo 36(NO)4O108(H2O)16)} Cl0.67 • 29.5H2O and (H3O) 5[{Tm(H2O)6}2{Tm(H 2O)4} {Mo36(NO)4 O 108(H2O)16}]Cl2 • 45H 2O, respectively, in which the polyoxometalate fragments are linked to each other by lanthanide cations to form infinite chains.

Original languageEnglish (US)
Pages (from-to)78-82
Number of pages5
JournalRussian Chemical Bulletin
Volume57
Issue number1
DOIs
StatePublished - Jan 1 2008

Keywords

  • Coordination polymers
  • Crystal structure
  • Lanthanides
  • Molybdenum
  • Polyoxometalates

ASJC Scopus subject areas

  • Chemistry(all)

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