Synthesis and structures of metallated N-heterocyclic derivatives

Lukasz Ponikiewski, Weifeng Shi, Alexander Rothenberger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The synthesis and structures of five new compounds are reported. [Mg(6-Oq)2(phen)2] (1), [Na(phen)3][(6-HOq)(6- Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)2(PPh3)]∞ (3), 1/∞[Cu2{μ-(6-Oq)}(PPh3)2]∞ (4) and [Cu2(pht)2(μ-dppm)2] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1-5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.

Original languageEnglish (US)
Pages (from-to)1770-1774
Number of pages5
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume634
Issue number10
DOIs
StatePublished - Aug 1 2008

Keywords

  • Coordination polymers
  • Copper
  • Hydrogen bonding
  • Metal alkoxides
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Inorganic Chemistry

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