Synthesis and structure of [{Sb(μ-NCy)}2(μ-N)]3(Li·THF)3- (LiN=NH), containing a macrocyclic [{Sb(μ-NCy)}2N]33- trianion

Felipe García, David J. Linton, Mary McPartlin, Alexander Rothenberger, Andrew E.H. Wheatley, Dominic S. Wright*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Reaction of the Sb(III) dimer [Me2NSb(μ-NCy)]2 with Li-NH2 (1:2 equivalents, respectively) gives [{Sb(μ-NCy)}2N]3-(Li·THF)3 (LiN=NH)·0.25(dioxane) 4, in which four Li+ cations are coordinated within the trimeric cavity of the macrocyclic trianion [{Sb(μ-NCy)}2N]33-.

Original languageEnglish (US)
Pages (from-to)481-483
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number4
DOIs
StatePublished - Jan 1 2002

ASJC Scopus subject areas

  • Chemistry(all)

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