Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates

M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, Maxim Yutkin, A. V. Virovets, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Chiral metal-organic coordination polymers [Co2(sacch) 2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

Original languageEnglish (US)
Pages (from-to)716-721
Number of pages6
JournalRussian Chemical Bulletin
Volume62
Issue number3
DOIs
StatePublished - Mar 1 2013

Keywords

  • X-ray diffraction
  • chiral complexes
  • cobalt(ii) complexes
  • coordination polymers
  • copper(ii) complexes
  • magnesium complexes
  • saccharic acid

ASJC Scopus subject areas

  • Chemistry(all)

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