Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

Gérard Descotes*, Jan Ramza, Jean-Marie Maurice Basset, Salvatore Pagano, Emmanuel Gentil, Joseph Banoub

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted ω-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds.

Original languageEnglish (US)
Pages (from-to)10903-10920
Number of pages18
JournalTetrahedron
Volume52
Issue number33
DOIs
StatePublished - Aug 12 1996

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten'. Together they form a unique fingerprint.

Cite this