Synthesis and Optical Properties of a Dithiolate/Phosphine-Protected Au28 Nanocluster

Maha A. Aljuhani, Megalamane Siddaramappa Bootharaju, Lutfan Sinatra, Jean-Marie Basset, Omar F. Mohammed, Osman Bakr

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

While monothiols and simple phosphines are commonly exploited for size-controlled synthesis of atomically precise gold nanoclusters (NCs), dithiols or dithiol-phosphine combinations are seldom applied. Herein, we used a dithiol (benzene-1,3-dithiol, BDT) and a phosphine (triphenylphosphine, TPP) together as ligands and synthesized an atomically precise gold NC with the formula [Au28(BDT)4(TPP)9]2+. This NC exhibited multiple absorption features and a charge of +2, which are distinctly different from the reported all-thiolated [Au28(SR)20]0 NC (SR: monothiolate). The composition of [Au28(BDT)4(TPP)9]2+ NC was deduced from high-resolution electrospray ionization mass spectrometry (ESI MS) and it was further corroborated by thermogravimetric analysis (TGA). Differential pulse voltammetry (DPV) revealed a HOMO–LUMO gap of 1.27 eV, which is in good agreement with the energy gap of 1.3 eV obtained from its UV–vis spectrum. The successful synthesis of atomically precise, dithiol-protected Au28 NC would stimulate theoretical and experimental research into bidentate ligands as a new path for expanding the library of different metal NCs, which have so far been dominated by monodentate thiols.
Original languageEnglish (US)
Pages (from-to)10681-10685
Number of pages5
JournalThe Journal of Physical Chemistry C
Volume121
Issue number20
DOIs
StatePublished - Jan 4 2017

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