Synthesis and crystal structures of octahedral metal complexes containing the new dianion [PhP(Se,O)Se-Se(O,Se)PPh]2-

Weifeng Shi*, Le Zhang, Maryam Shafaei-Fallah, Alexander Rothenberger

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The synthesis and structures of three new compounds are reported. [Mg 2{PhP(Se,O)Se-Se(O,Se)PPh}2(thf)7(H 2O)3] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ-Se)]2 with the corresponding hydrated metal acetates.

Original languageEnglish (US)
Pages (from-to)440-442
Number of pages3
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume633
Issue number3
DOIs
StatePublished - Mar 5 2007

Keywords

  • Crystal structure
  • Magnesium
  • Manganese
  • Phosphorus
  • Selenium

ASJC Scopus subject areas

  • Inorganic Chemistry

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