Synthese und kristallstruktur von [(Me3Si)2BiCu(PMe3)3], dem ersten komplex mit einer bismut-kupfer-bindung

Translated title of the contribution: Synthesis and crystal structure of [(Me3Si)2BiCu(PMe3)3] - The first complex with a bismuth-copper bond

Dieter Fenske*, Alexander Rothenberger, Stephan Wieber

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The reaction of CuOtBu with PMe3 and Bi(SiMe3)3 in hexane yields the phosphine-stabilized complex [(Me3Si)2Bi-Cu(PMe3)3]. This synthesis gave rise to the first binuclear Bi-Cu compound to be structurally characterized by X-ray crystallography.

Translated title of the contributionSynthesis and crystal structure of [(Me3Si)2BiCu(PMe3)3] - The first complex with a bismuth-copper bond
Original languageGerman
Pages (from-to)929-930
Number of pages2
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume629
Issue number6
DOIs
StatePublished - Jun 24 2003

Keywords

  • Bismuth
  • Cluster
  • Copper
  • Crystal structure

ASJC Scopus subject areas

  • Inorganic Chemistry

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