Synthesis and characterization of substituted poly(ferrocenylsilanes) and magnetic properties of their doped products

Yunyang Liu, Hongding Tang, Xu Su, Xingguo Chen, Jun Li, Jingui Qin*, Xixiang Zhang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A new series of substituted poly(ferrocenylsilane) (3a-3c) were synthesized through transition-metal catalyzed ring-opening polymerization (ROP) of the corresponding silaferrocenophanes (2a-2c). The structural characterization is presented with 1H-NMR, FT-IR, gel permeation chromatography (GPC), and differential scanning calorimeter (DSC). These polymers were doped with tetracyanoethylene (TCNE). The magnetic property of doped product (4c) was studied by SQUID measurement, and which indicated that this doped product showed paramagnetism with below 110 K.

Original languageEnglish (US)
Pages (from-to)171-172
Number of pages2
JournalSynthetic Metals
Volume135-136
DOIs
StatePublished - Apr 4 2003

Keywords

  • Magnetic measurements
  • Poly(ferrocenylsilanes)
  • Synthesis
  • Transition-metal catalyzed reaction

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Synthesis and characterization of substituted poly(ferrocenylsilanes) and magnetic properties of their doped products'. Together they form a unique fingerprint.

Cite this