Synthesis and characterization of second-generation phosphorus-nitrogen PN 3 P-rhodium (I) pincer complexes via ligand post-modification

Chunhui Zhou, Jinsong Hu, Priyanka Chakraborty, Kuo-Wei Huang

Research output: Contribution to journalArticlepeer-review

Abstract

A pseudo-dearomatized PN3P*Rh−CO complex reacts with various alkyl/benzyl halides to furnish a series of second-generation PN3P-pincer carbonyl complexes via the ligand post-modification strategy. These synthesized complexes were fully characterized by NMR, FTIR, HRMS, and single-crystal X-ray crystallography. A plausible mechanism for the formation of 2nd-generation PN3P complexes was proposed based on the isolation of the minor dialkylated products.
Original languageEnglish (US)
JournalZeitschrift für anorganische und allgemeine Chemie
DOIs
StatePublished - May 7 2021

ASJC Scopus subject areas

  • Inorganic Chemistry

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