Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups

Chun Qing Liu, Yang Liu, Ping Xie, Rong Ben Zhang*, Chao Bin He, Tai-Shung Chung

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

Original languageEnglish (US)
Pages (from-to)1-6
Number of pages6
JournalChinese Journal of Polymer Science (English Edition)
Volume19
Issue number1
StatePublished - Dec 1 2001

Keywords

  • Characterization
  • Equilibration polymerization
  • Hydrosilylation
  • Polyorganosiloxane

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Organic Chemistry
  • Polymers and Plastics

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