Synthesen und strukturen von übergangsmetall-komplexen mit dithiophosphinato- und trithiophosphonato-liganden

Translated title of the contribution: Syntheses and structures of transition metal complexes with dithiophosphinato and trithiophosphinato ligands

Maryam Shafaei-Fallah*, Weifeng Shi, Dieter Fenske, Alexander Rothenberger

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The reactions of MnCl2 with Ph2P(S)(SSiMe 3) produced [Mn(S2PPh2)2(thf) 2] (1) and [Mn(S2PPh2)2(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co6(S3PPh) 24-S)23-S) 2(PPh3)4] (3), [Co2(S 3PPh)2(PPh3)2] (4), [Ni(S 2PPh)(PPhEt2)2] (5), [Ni(S3PPh) (PPhEt2)2] (6) and [Cu4(S3PPh) 2(dppp)2] (8) [dppp = 1,3-Bis(diphenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe3)2 in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe3)2 with PhPEt2 PhPEt2PS2Ph (7) was isolated. All compounds were characterized by X-ray crystallography.

Translated title of the contributionSyntheses and structures of transition metal complexes with dithiophosphinato and trithiophosphinato ligands
Original languageGerman
Pages (from-to)1091-1096
Number of pages6
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume632
Issue number6
DOIs
StatePublished - May 18 2006

Keywords

  • Cobalt
  • Crystal structures
  • Manganese
  • Nickel
  • P ligands
  • S ligands

ASJC Scopus subject areas

  • Inorganic Chemistry

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