Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden

Translated title of the contribution: Syntheses and crystal structures of copper and silver complexes containing dithiophosphinato and trithiophosphonato ligands

Dieter Fenske*, Alexander Rothenberger, Maryam Shafaei Fallah

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The reactions of Cu1 and Ag1 salts with diphenyldithiophosphinic acid trimethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(μ-S)SPPh2(PR3)] 2 (R = Me 1a, iPr 1b), [Ag(μ-S)SPPh2(P nPr3)]2 (2), [Ag(S2PPh 2)(PEt3)]2 (3), and [Cu88-S)(S2PPh2)6] (4). The cage complex [(PhPS3)2Cu4(PMe3)5] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by X-ray crystallography.

Translated title of the contributionSyntheses and crystal structures of copper and silver complexes containing dithiophosphinato and trithiophosphonato ligands
Original languageGerman
Pages (from-to)943-947
Number of pages5
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume630
Issue number6
DOIs
StatePublished - 2004
Externally publishedYes

Keywords

  • Copper
  • Crystal structures
  • P Ligands
  • S Ligands
  • Silver

ASJC Scopus subject areas

  • Inorganic Chemistry

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