Surface organometallic chemistry on oxides: The first well-defined selenium(IV) derivative grafted onto silica

Hélène Provendier, Catherine C. Santini*, Jean-Marie Maurice Basset, Laurent Carmona

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Treatment of (EtO)2SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO-Se(O)OEt] (1), which has been fully characterized by elemental analysis, IR, labelling reaction and solid-state NMR spectroscopy. This is the first example of a silica-supported selenium(IV) derivative. (

Original languageEnglish (US)
Pages (from-to)2139-2144
Number of pages6
JournalEuropean Journal of Inorganic Chemistry
Issue number11
DOIs
StatePublished - Jan 1 2003

Keywords

  • Acetaldehyde
  • Oxidation
  • Selenium
  • Supported catalysis
  • Surface chemistry

ASJC Scopus subject areas

  • Inorganic Chemistry

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