Steric and electronic parameters of a bulky yet flexible N-heterocyclic carbene: 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

Alba Collado, János Balogh, Sébastien Meiries, Alexandra M. Z. Slawin, Laura Falivene, Luigi Cavallo, Steven P. Nolan

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

The free N-heterocyclic carbene IPent (1; IPent = 1,3-bis(2,6-bis(1- ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel-carbonyl complex [Ni(IPent)(CO)3] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals. © 2013 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)3249-3252
Number of pages4
JournalOrganometallics
Volume32
Issue number11
DOIs
StatePublished - May 28 2013

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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