Stereochemical behaviour of cis- and trans-cyclo-octene in metathesis

C. Larroche*, J. P. Laval, A. Lattes, M. Leconte, F. Quignard, J. M. Basset

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

With the catalyst Mo(NO)2Cl2(PPh3) 2 + EtAlCl2, cis- and trans-cyclo-octenes give respectively cis- and trans-polyoctenes; cyclic and acyclic olefins have a similar stereochemical behaviour in metathesis but, depending on the strain of the ring, the expected retention of configuration of the starting olefin may be attenuated.

Original languageEnglish (US)
Pages (from-to)220-221
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
StatePublished - 1983
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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