Soluble and stable zethrenebis(dicarboximide) and its quinone

Zhe Sun, Kuo-Wei Huang, Jishan Wu

Research output: Contribution to journalArticlepeer-review

61 Scopus citations

Abstract

Soluble and stable zethrenebis(dicarboximide) (1) was synthesized by an in situ Stille cross coupling/transannular cyclization reaction. 1 showed largely improved photostability and solubility compared with the very unstable zethrene and it also exhibited far-red absorption and emission with high photoluminescence quantum yield. Bromination of 1 with NBS/DMF gave its quinone form 2 via an unusual pathway. © 2010 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)4690-4693
Number of pages4
JournalOrganic Letters
Volume12
Issue number20
DOIs
StatePublished - Oct 15 2010

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry

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