Slowing down the deactivation of H-ZSM-5 zeolite catalyst in the methanol-to-olefin (MTO) reaction by P or Zn modifications

José Valecillos, Eva Epelde, Jonathan Albo, Andrés T. Aguayo, Javier Bilbao, Pedro Castaño

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The benefits of H-ZSM-5 zeolite modification with H3PO4 or ZnCl2 have been analyzed during the methanol to olefins (MTO) reaction. The catalysts were prepared, characterized and tested using three different reactors: fixed-bed, operando FTIR and UV–vis. The spent catalysts were further characterized for analyzing the nature and location of the species trapped. The results show that the zeolite modified with H3PO4 has suffered a simultaneous dealumination, leading to a decrease of number of acid sites and activity. However, the zeolite modified with ZnCl2 shows the inclusion of Zn transforming Brønsted into Lewis acid sites, leading to reaction intermediates (hydrocarbon pool species) that decreases the rate of reaction but improves propylene selectivity (+10%), slows downs coke formation (-42%) and expands catalytic lifetime (+80%). The distinct effect of Zn modification, typically associated with the promotion of aromatics, is explained on the grounds of the severe transformation of the strong and Brønsted acid sites.
Original languageEnglish (US)
JournalCatalysis Today
DOIs
StatePublished - Aug 5 2019

Fingerprint Dive into the research topics of 'Slowing down the deactivation of H-ZSM-5 zeolite catalyst in the methanol-to-olefin (MTO) reaction by P or Zn modifications'. Together they form a unique fingerprint.

Cite this