[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface

Yin Chen, Emmanuel Callens, Edy Abou-Hamad, Jean-Marie Basset

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.
Original languageEnglish (US)
Pages (from-to)3-6
Number of pages4
JournalJournal of Organometallic Chemistry
Volume744
DOIs
StatePublished - Nov 2013

ASJC Scopus subject areas

  • Materials Chemistry
  • Biochemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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