TY - JOUR
T1 - Shifting from Ziegler-Natta to Philips-type catalyst? A simple and safe access to reduced titanium systems for ethylene polymerization
AU - Popoff, Nicolas
AU - Espinas, Jeff
AU - Gouré, Eric
AU - Boyron, Olivier
AU - Le Roux, Erwan
AU - Basset, Jean-Marie
AU - Gauvin, Régis M.
AU - De Mallmann, Aimery
AU - Taoufik, Mostafa
N1 - KAUST Repository Item: Exported on 2020-10-01
PY - 2011/9/22
Y1 - 2011/9/22
N2 - Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - Silica-supported titanium(IV) chloride is readily reduced by Mashima and co-workers' reagent (1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene) to afford materials active in ethylene polymerisation without need of aluminum alkyl cocatalyst. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
UR - http://hdl.handle.net/10754/566032
UR - http://doi.wiley.com/10.1002/marc.201100477
UR - http://www.scopus.com/inward/record.url?scp=82455175746&partnerID=8YFLogxK
U2 - 10.1002/marc.201100477
DO - 10.1002/marc.201100477
M3 - Article
C2 - 21948353
VL - 32
SP - 1921
EP - 1924
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
SN - 1022-1336
IS - 23
ER -