Selective catalytic hydrogenation of aromatic compounds is extremely challenging using transition-metal catalysts. Hydrogenation of arenols to substituted tetrahydronaphthols or cyclohexanols has been reported only with heterogeneous catalysts. Herein, we demonstrate the selective hydrogenation of arenols to the corresponding tetrahydronaphthols or cyclohexanols catalyzed by a phenanthroline-based PN3-ruthenium pincer catalyst.
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CCDC 1531043: Experimental Crystal Structure Determination : (N-[2,2'-bipyridin]-6-yl-P,P-di-t-butylphosphinous amide)-carbonyl-chloro-hydrido-ruthenium
CCDC 1531042: Experimental Crystal Structure Determination : carbonyl-chloro-(P,P-di-t-butyl-N-1,10-phenanthrolin-2-ylphosphinous amide)-hydrido-ruthenium methanol solvate