Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

André Dragässer, Osama Shekhah, Olexandra Zybaylo, Cai Shen, Manfred Buck, Christof Wöll*, Derck Schlettwein

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

Original languageEnglish (US)
Pages (from-to)663-665
Number of pages3
JournalChemical Communications
Volume48
Issue number5
DOIs
StatePublished - Jan 18 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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