Reaction of "[MnII(CH2tBu)2]" with bidentate diimine ligands: From simple base adducts to C-C activation of the ligand

Virginie Riollet, Christophe Copéret*, Jean Marie Basset, Laurence Rousset, Denis Bouchu, Laurent Grosvalet, Monique Perrin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Ligand transformations that depend on the substitution patterns of the diimine ligands occur upon their complexation with Mn11 dialkyl complexes. For example the 1,3-migration of the neopentyl unit from Mn to a carbon atom and the 1,2-migration of the methyl in the putative intermediate 1 give the product 2.

Original languageEnglish (US)
Pages (from-to)3025-3027
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number16
DOIs
StatePublished - Aug 16 2002

Keywords

  • C-C activation
  • Chelates
  • Manganese
  • N ligands

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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