Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Zhenjie Zhang, Wenyang Gao, Łukasz Wojtas, Shengqian Ma, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journalArticlepeer-review

98 Scopus citations

Abstract

Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish (US)
Pages (from-to)9330-9334
Number of pages5
JournalAngewandte Chemie International Edition
Volume51
Issue number37
DOIs
StatePublished - Aug 21 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

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