Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih Salem Al-Juaid, Joseph T. Hupp, Omar K. Farha

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
Original languageEnglish (US)
Pages (from-to)85-88
Number of pages4
JournalChem. Commun.
Volume51
Issue number1
DOIs
StatePublished - 2015

ASJC Scopus subject areas

  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Ceramics and Composites
  • Chemistry(all)
  • Catalysis
  • Electronic, Optical and Magnetic Materials

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