Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality

Peng Yang; Wenli zhao; Aleksander Shkurenko; Youssef Belmabkhout; Mohamed Eddaoudi; Xiaochen Dong; Husam N. Alshareef; Niveen M. Khashab

doi:10.1021/jacs.8b11998

Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality

Peng Yang, Wenli zhao, Aleksander Shkurenko, Youssef Belmabkhout, Mohamed Eddaoudi, Xiaochen Dong, Husam N. Alshareef, Niveen M. Khashab

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.

Original language	English (US)
Pages (from-to)	1847-1851
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	141
Issue number	5
DOIs	https://doi.org/10.1021/jacs.8b11998
State	Published - Jan 4 2019

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10.1021/jacs.8b11998

https://repository.kaust.edu.sa/bitstream/10754/630779/1/jacs.8b11998.pdf

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Yang, Peng ; zhao, Wenli ; Shkurenko, Aleksander ; Belmabkhout, Youssef ; Eddaoudi, Mohamed ; Dong, Xiaochen ; Alshareef, Husam N. ; Khashab, Niveen M. / Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 5. pp. 1847-1851.

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title = "Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality",

abstract = "Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.",

author = "Peng Yang and Wenli zhao and Aleksander Shkurenko and Youssef Belmabkhout and Mohamed Eddaoudi and Xiaochen Dong and Alshareef, {Husam N.} and Khashab, {Niveen M.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors acknowledge Dr. G. Mouchaham and Dr. O. El-Tall for technical assistance.",

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Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality. / Yang, Peng; zhao, Wenli; Shkurenko, Aleksander; Belmabkhout, Youssef; Eddaoudi, Mohamed; Dong, Xiaochen; Alshareef, Husam N.; Khashab, Niveen M.

In: Journal of the American Chemical Society, Vol. 141, No. 5, 04.01.2019, p. 1847-1851.

Research output: Contribution to journal › Article › peer-review

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AU - Yang, Peng

AU - zhao, Wenli

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AU - Belmabkhout, Youssef

AU - Eddaoudi, Mohamed

AU - Dong, Xiaochen

AU - Alshareef, Husam N.

AU - Khashab, Niveen M.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors acknowledge Dr. G. Mouchaham and Dr. O. El-Tall for technical assistance.

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N2 - Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.

AB - Self-assembly allows structures to organize themselves into regular patterns by using local forces to find the lowest-energy configuration. However, assembling organic and inorganic building blocks in an ordered framework is hampered by the difficulties of interfacing two dissimilar materials. Herein, the ensemble of polyoxometalates (POMs) and cyclodextrins (CDs) as molecular building blocks (MBBs) has yielded two unprecedented POM-CD-MOFs, namely [PW12O40]3− & α-CD MOF (POT-CD) and [P10P15.5O50]19− & γ-CD MOF (POP-CD), with distinct properties not shared by their isolated parent MBBs. Markedly, the POT-CD features a nontraditional enhanced Li storage behavior by virtue of a unique “amorphization & pulverization” process. This opens the door to a new generation of hybrid materials with tuned structures and customized functionalities.

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Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality

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CCDC 1870923: Experimental Crystal Structure Determination : alpha-cyclodextrin potassium sodium (mu-phosphato)-tetracosakis(mu-oxo)-dodecaoxo-dodeca-tungsten acetate hydroxide nonadecahydrate

CCDC 1870924: Experimental Crystal Structure Determination : gamma-cyclodextrin tricosa-potassium octakis(mu-hydrogen phosphato)-decakis(mu-oxo)-bis(mu-phosphato)-hexadeca-palladium heptakis(mu-hydrogen phosphato)-decakis(mu-oxo)-tris(mu-phosphato)-pentade

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Polyoxometalate−Cyclodextrin Metal−Organic Frameworks: From Tunable Intrinsic Microporosity to Customized Storage Functionality

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CCDC 1870923: Experimental Crystal Structure Determination : alpha-cyclodextrin potassium sodium (mu-phosphato)-tetracosakis(mu-oxo)-dodecaoxo-dodeca-tungsten acetate hydroxide nonadecahydrate

CCDC 1870924: Experimental Crystal Structure Determination : gamma-cyclodextrin tricosa-potassium octakis(mu-hydrogen phosphato)-decakis(mu-oxo)-bis(mu-phosphato)-hexadeca-palladium heptakis(mu-hydrogen phosphato)-decakis(mu-oxo)-tris(mu-phosphato)-pentade

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