Polymeric Reagents. Preparation of Resins Containing Polyvinylperbenzoic Acid Units1

Jean Frechet, Kazi E. Haque

Research output: Contribution to journalArticlepeer-review

61 Scopus citations

Abstract

Several synthetic routes to bead polymers containing peracid functional groups have been explored. Thus, swellable or macroreticular styrene-divinylbenzene copolymers containing approximately 1 mequiv of perbenzoic acid functional group per gram were prepared from resins containing vinylbenzoic acid, vinylbenzoyl chloride, or vinylbenzaldehyde units. The polymeric peracids were stable and could be used and regenerated several times without degradation. The use of the polymers in a simple epoxidation reaction is described.

Original languageEnglish (US)
Pages (from-to)130-134
Number of pages5
JournalMacromolecules
Volume8
Issue number2
DOIs
StatePublished - Mar 1 1975

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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